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Yunfei Du ——Professor
Nationality:
CHINA
Phone:
022-27406121
Email:
duyunfeier@tju.edu.cn
Office:
Room A208, Building 24, Tianjin University
School:
School of Pharmaceutical Science and Technology
ResearcherID:
K-3776-2015
Group weblink
Education Experience
2007 Ph. D. Tianjin University, CN
Professional Experience
2007-2009 Assistant Professor Tianjin University.
2009-2013 Associate Professor Tianjin University
2012-2019 Associate Dean / Party Vice-Secretary Tianjin University
2013-2019 Professor Tianjin University
2019- Associate Dean Tianjin U
Research Area

The research area of the Du group involves investigation of hypervalent iodine (III) – mediated transformations, including oxidative coupling, rearrangement, cascade reactions, and asymmetric reactions.  Additionally, the group develops metal-free methodology for the constructionof heterocyclic compounds and pharmaceutical agents.

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Honors and Awards
四乙酰核糖和二乙酰阿昔洛韦合成的新工艺，天津市人民政府，科技进步奖，二等奖，2010。（赵康、陈维瑜、魏静、杜云飞、王松青、苏艳芳、张秀东、陈炎泉）
第十二届“挑战杯”天津市大学生课外学术科技作品竞赛优秀指导教师，天津市委员会、天津市科学技术委员会、天津市教育工作委员会等，优秀指导教师，2013。（杜云飞）
天津大学“北洋青年学者”，2015年。
天津市“131”创新型人才培养工程第一层次人选，2016年。
Patents
杜云飞，袁玉成，赵康，一种通过C–N氧化偶联合成取代二氨基烯烃衍生物的方 法，中国，2014104793464
杜云飞，程然，赵康，一种通过环合消除一锅法合成4（3H）-喹唑啉酮衍生物的 方法，中国，201410113565.0。
杜云飞，程然，赵康，一种通过环合消除一锅法合成4（3H）-喹唑啉酮衍生物的 方法，中国，201410113565.0。
杜云飞，尚巳耘，赵康，一种合成二苯并二氢-1,3-二氮杂䓬类衍生物的方法， 中国，201310608894.8。
杜云飞，吕晶磊，赵康，一种2-吲哚酮-3-羧酸酯类衍生物的合成方法，中国，2 01310503250.2。
杜云飞，李旭明，张翔，赵康，一种二苯西平类衍生物的合成方法，中国，2013 10455049.1。
杜云飞，吕晶磊，尚巳耘，赵康，一种四氢-γ-咔啉类衍生物的合成方法，中 国，201310022038.4。
杜云飞，刘乐，贺巧巧，赵康，1,3-二腈基2-取代-1H-茚类衍生物及其制备方 法，中国，201210044059.1。
杜云飞，赵康，赵菲菲，刘昕，齐蕊，2-三氟甲基噁唑类衍生物的合成方法， 中国，201110120698.7。
杜云飞，云希柳，毕文英，赵康，一种氮取代四氢咔唑酮衍生物的制备新方法 ，中国，201010252043.0。
祁秀香，杜云飞，闫俏，赵康，李慧，合成N-芳基吲哚-3-腈衍生物的方法，中 国，201010560853.2。
杜云飞，汤丽娜，庞永乐，阎俏，祁秀香，一种合成Coumestan类衍生物的新方 法，中国，201010171129.0。
杜云飞，马辉，赵康，异吲哚啉羧酸酯衍生物的制备方法及其应用，中国，201 010187238.1。
Highlighted Publications
Shang, S.; Zhang-Negrerie, D.; Du, Y.;* Zhao, K.* Intramolecular Metal-free Oxidative Aryl-aryl Coupling: An Unusual Hypervalent Iodine-mediated Rearrangement of 2-Substituted N-Phenylbenzamides. Angew. Chem., Int. Ed. 2014, 53, 6216. (Hot Paper)
Yu, J.; Zhang-Negrerie, D.; Du, Y.* Cu(OAc)2-Mediated Cascade Annulation of Diarylalkyne Sulfonamides through Dual C-N Bond Formation: Synthesis of 5,10-Dihydroindolo[3,2-b]indoles. Org. Lett. 2016, 18, 3322–3325.
Cao, Y.; Zhang, X.; Lin, G.; Zhang-Negrerie, D.; Du, Y.* Chiral Aryliodine-Mediated Enantioselective Organocatalytic Spirocyclization: Synthesis of Spirofurooxindoles via Cascade Oxidative C-O and C-C Bond Formation. Org. Lett. 2016, 18, 5580–5583.
Zhang, B.; Zhang,X.; Hu, B.; Sun, D.; Wang, S.; Zhang-Negrerie, D.; Du. Y.* PhI(OCOCF3)2-Mediated Construction of 2-Spiropseudoindoxyl Skeleton via Cascade Annulation of 2-Sulfonamido-N-phenylpropiolamide Derivatives. Org. Lett. 2017, 19, 902.
Zhao, X.; Li, Q.; Xu, J.; Wang, D.; Zhang-Negrerie, D.; Du, Y.* Cascade Synthesis of Benzothieno[3,2-b]indoles Under Oxidative Conditions Mediated by CuBr and tert-Butyl Hydroperoxide. Org. Lett. 2018, 20, 5933-5937.
ResearcherID Publications
Year Title Author(s) Source Volume
2012 Copper(II)-Mediated Cascade Oxidative C-C Coupling and Aromatization: Synthesis of 3-Hydroxyphenanthridinone Derivatives Yu, Qingzhen; Zhang, Nan; Tang, Yang; et al. Synthesis-Stuttgart 44
2012 Direct beta-Acyloxylation of Enamines via PhIO-Mediated Intermolecular Oxidative C-O Bond Formation and Its Application to the Synthesis of Oxazoles Liu, Xin; Cheng, Ran; Zhao, Feifei; et al. Organic Letters 14
2012 Phenyliodine Bis(trifluoroacetate)-Mediated Oxidative C-C Bond Formation: Synthesis of 3-Hydroxy-2-oxindoles and Spirooxindoles from Anilides Wang, Junwei; Yuan, Yucheng; Xiong, Rui; et al. Organic Letters 14
2012 Synthesis of carbazolones and 3-acetylindoles via oxidative C-N bond formation through PIFA-mediated annulation of 2-aryl enaminones Ban, Xu; Pan, Yan; Lin, Yingfu; et al. Organic & Biomolecular Chemistry 10
2012 Synthesis of Functionalized Fluorescent Indenes from Electron-Rich alpha-Aryl Ketonitriles Liu, Le; Fan, Yanfeng; He, Qiaoqiao; et al. Journal of Organic Chemistry 77
2012 Synthesis of N-substituted carbazolones from alpha-iodo enaminones via Pd(0)-catalyzed intramolecular coupling under microwave irradiation Yun, Xi-Liu; Bi, Wen-Ying; Huang, Jian-Hui; et al. Tetrahedron Letters 53
2012 Synthesis of Oxazoles from Enamides via Phenyliodine Diacetate-Mediated Intramolecular Oxidative Cyclization Zheng, Yunhui; Li, Xuming; Ren, Chengfeng; et al. Journal of Organic Chemistry 77
2011 Oxidative aromatic C-N bond formation: convenient synthesis of N-amino-3-nitrile-indoles via FeBr3-mediated intramolecular cyclization Zheng, Zisheng; Tang, Lina; Fan, Yanfeng; et al. Organic & Biomolecular Chemistry 9
2011 Synthesis of 1,2-Diketones from beta-Keto Nitriles via a Protection-Oxidative-Decyanation-Deprotection Protocol Liu, Yu; Yun, Xiliu; Zhang-Negrerie, Daisy; et al. Synthesis-Stuttgart
2011 Synthesis of 2-(Trifluoromethyl)oxazoles from beta-Monosubstituted Enamines via Phl(OCOCF3)(2)-Mediated Trifluoroacetoxylation and Cyclization Zhao, Feifei; Liu, Xin; Qi, Rui; et al. Journal of Organic Chemistry 76

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